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However, current photodetectors rely on p-type CQD layers fabricated via a laborious, defect-prone layer-by-layer process. While robust n-type CQD inks have been realized, p-type inks remain challenging due to the absence of suitable ligands and solvents. An ideal solvent must ensure colloidal stability and be orthogonal to underlying layers. Here, we report a thiolate-capped p-type PbS CQD ink using mercapto-2-propanol as the ligand and hexafluoro-2-propanol as the solvent. Stabilization arises from ligand–solvent hydrogen bonding, providing a shelf-life exceeding six days. The solvent does not compromise pre-deposited layers, enabling fully blade-coated photodiodes in both n–p and p–n architectures. Devices fabricated with this ink exhibit a twofold increase in specific detectivity (2.55 × 1012 Jones) and a 70% enhancement in bandwidth (155 kHz) compared to layer-by-layer controls, attributed to improved film morphology and charge transport."},"dsDescriptionDate":{"typeName":"dsDescriptionDate","multiple":false,"typeClass":"primitive","value":"2025"}}]},{"typeName":"subject","multiple":true,"typeClass":"controlledVocabulary","value":["Chemistry","Physics"]},{"typeName":"keyword","multiple":true,"typeClass":"compound","value":[{"keywordValue":{"typeName":"keywordValue","multiple":false,"typeClass":"primitive","value":"lead sulfide quantum dot"}},{"keywordValue":{"typeName":"keywordValue","multiple":false,"typeClass":"primitive","value":"short-wavelength infrared"}},{"keywordValue":{"typeName":"keywordValue","multiple":false,"typeClass":"primitive","value":"blade coating"}},{"keywordValue":{"typeName":"keywordValue","multiple":false,"typeClass":"primitive","value":"phase-transfer ligand exchange"}},{"keywordValue":{"typeName":"keywordValue","multiple":false,"typeClass":"primitive","value":"p-type ink"}},{"keywordValue":{"typeName":"keywordValue","multiple":false,"typeClass":"primitive","value":"photodetector"}}]},{"typeName":"publication","multiple":true,"typeClass":"compound","value":[{"publicationRelationType":{"typeName":"publicationRelationType","multiple":false,"typeClass":"controlledVocabulary","value":"IsSupplementTo"},"publicationCitation":{"typeName":"publicationCitation","multiple":false,"typeClass":"primitive","value":"Han Wang, Jiaxiong Li, Jacopo Pinna, Mordechai Kot, Noah Y. N. van der Ploeg, Maria A. Loi. Advanced Materials,2026; 0:e18118."},"publicationURL":{"typeName":"publicationURL","multiple":false,"typeClass":"primitive","value":"https://doi.org/10.1002/adma.202518118"}}]},{"typeName":"notesText","multiple":false,"typeClass":"primitive","value":"The dataset contains the raw data of the experiments performed for the scientific article \"Stable P-Type PbS Quantum Dot Ink for All-Blade-Coated Short-Wavelength Infrared Photodiodes\".\nThe dataset contains data from UV-vis spectroscopy, transistor measurements, and photodetector characterization.\nAll data was converted to .Dat format that can be opened by Microsoft Excel or a Notepad (instructions on how to open the data are present). 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