{"status":"OK","data":{"id":384645,"identifier":"SAXZOK","persistentUrl":"https://doi.org/10.34894/SAXZOK","protocol":"doi","authority":"10.34894","separator":"/","publisher":"DataverseNL","publicationDate":"2023-11-16","storageIdentifier":"surf://10.34894/SAXZOK","effectiveDatasetFileCountLimit":10000,"datasetFileUploadsAvailable":9999,"datasetType":"dataset","locks":[],"latestVersion":{"id":25513,"datasetId":384645,"datasetPersistentId":"doi:10.34894/SAXZOK","datasetType":"dataset","storageIdentifier":"surf://10.34894/SAXZOK","versionNumber":1,"internalVersionNumber":13,"versionMinorNumber":0,"versionState":"RELEASED","latestVersionPublishingState":"RELEASED","deaccessionLink":"","lastUpdateTime":"2023-11-16T15:37:31Z","releaseTime":"2023-11-16T15:37:31Z","createTime":"2023-11-08T09:52:45Z","publicationDate":"2023-11-16","citationDate":"2023-11-16","effectiveDatasetFileCountLimit":10000,"datasetFileUploadsAvailable":9999,"license":{"name":"CC0-1.0","uri":"http://creativecommons.org/publicdomain/zero/1.0","iconUri":"https://licensebuttons.net/p/zero/1.0/88x31.png","rightsIdentifier":"CC0-1.0","rightsIdentifierScheme":"SPDX","schemeUri":"https://spdx.org/licenses/","languageCode":"en"},"fileAccessRequest":false,"metadataBlocks":{"citation":{"displayName":"Citation 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Groningen"},"authorIdentifierScheme":{"typeName":"authorIdentifierScheme","multiple":false,"typeClass":"controlledVocabulary","value":"ORCID"},"authorIdentifier":{"typeName":"authorIdentifier","multiple":false,"typeClass":"primitive","value":"0000-0003-0063-0742"}},{"authorName":{"typeName":"authorName","multiple":false,"typeClass":"primitive","value":"Sebastian Alonso, Javier"},"authorAffiliation":{"typeName":"authorAffiliation","multiple":false,"typeClass":"primitive","value":"Universitat de Valencia"},"authorIdentifierScheme":{"typeName":"authorIdentifierScheme","multiple":false,"typeClass":"controlledVocabulary","value":"ORCID"},"authorIdentifier":{"typeName":"authorIdentifier","multiple":false,"typeClass":"primitive","value":"0000-0003-3687-3156"}},{"authorName":{"typeName":"authorName","multiple":false,"typeClass":"primitive","value":"Di Mario, Lorenzo"},"authorAffiliation":{"typeName":"authorAffiliation","multiple":false,"typeClass":"primitive","value":"University of Groningen"},"authorIdentifierScheme":{"typeName":"authorIdentifierScheme","multiple":false,"typeClass":"controlledVocabulary","value":"ORCID"},"authorIdentifier":{"typeName":"authorIdentifier","multiple":false,"typeClass":"primitive","value":"0000-0001-9722-1528"}},{"authorName":{"typeName":"authorName","multiple":false,"typeClass":"primitive","value":"Garcia Romero, David"},"authorAffiliation":{"typeName":"authorAffiliation","multiple":false,"typeClass":"primitive","value":"University of Groningen"},"authorIdentifierScheme":{"typeName":"authorIdentifierScheme","multiple":false,"typeClass":"controlledVocabulary","value":"ORCID"},"authorIdentifier":{"typeName":"authorIdentifier","multiple":false,"typeClass":"primitive","value":"0000-0002-2918-5542"}},{"authorName":{"typeName":"authorName","multiple":false,"typeClass":"primitive","value":"Tran, Karolina"},"authorAffiliation":{"typeName":"authorAffiliation","multiple":false,"typeClass":"primitive","value":"University of Groningen"},"authorIdentifierScheme":{"typeName":"authorIdentifierScheme","multiple":false,"typeClass":"controlledVocabulary","value":"ORCID"},"authorIdentifier":{"typeName":"authorIdentifier","multiple":false,"typeClass":"primitive","value":"0000-0001-5432-5204"}},{"authorName":{"typeName":"authorName","multiple":false,"typeClass":"primitive","value":"Zaharia, Teodor"},"authorAffiliation":{"typeName":"authorAffiliation","multiple":false,"typeClass":"primitive","value":"University of Groningen"},"authorIdentifierScheme":{"typeName":"authorIdentifierScheme","multiple":false,"typeClass":"controlledVocabulary","value":"ORCID"},"authorIdentifier":{"typeName":"authorIdentifier","multiple":false,"typeClass":"primitive","value":"0009-0006-5156-2304"}},{"authorName":{"typeName":"authorName","multiple":false,"typeClass":"primitive","value":"Johansson, Malin"},"authorAffiliation":{"typeName":"authorAffiliation","multiple":false,"typeClass":"primitive","value":"Uppsala University"},"authorIdentifierScheme":{"typeName":"authorIdentifierScheme","multiple":false,"typeClass":"controlledVocabulary","value":"ORCID"},"authorIdentifier":{"typeName":"authorIdentifier","multiple":false,"typeClass":"primitive","value":"0000-0003-2046-1229"}},{"authorName":{"typeName":"authorName","multiple":false,"typeClass":"primitive","value":"Johansson, Erik"},"authorAffiliation":{"typeName":"authorAffiliation","multiple":false,"typeClass":"primitive","value":"Uppsala University"},"authorIdentifierScheme":{"typeName":"authorIdentifierScheme","multiple":false,"typeClass":"controlledVocabulary","value":"ORCID"},"authorIdentifier":{"typeName":"authorIdentifier","multiple":false,"typeClass":"primitive","value":"0000-0001-9358-8277"}},{"authorName":{"typeName":"authorName","multiple":false,"typeClass":"primitive","value":"Loi, Antonietta Maria"},"authorAffiliation":{"typeName":"authorAffiliation","multiple":false,"typeClass":"primitive","value":"University of Groningen"},"authorIdentifierScheme":{"typeName":"authorIdentifierScheme","multiple":false,"typeClass":"controlledVocabulary","value":"ORCID"},"authorIdentifier":{"typeName":"authorIdentifier","multiple":false,"typeClass":"primitive","value":"0000-0002-7985-7431"}}]},{"typeName":"datasetContact","multiple":true,"typeClass":"compound","value":[{"datasetContactName":{"typeName":"datasetContactName","multiple":false,"typeClass":"primitive","value":"Groningen Digital Competence Centre"},"datasetContactAffiliation":{"typeName":"datasetContactAffiliation","multiple":false,"typeClass":"primitive","value":"University of Groningen"}}]},{"typeName":"dsDescription","multiple":true,"typeClass":"compound","value":[{"dsDescriptionValue":{"typeName":"dsDescriptionValue","multiple":false,"typeClass":"primitive","value":"Mixed tin/lead (Sn/Pb) perovskites have the potential to achieve higher performances in single junction solar cells compared to Pb-based compounds. The best Sn/Pb based devices are fabricated in a p-i-n structure, and PEDOT:PSS is frequently utilized as the hole transport layer, even if there are many doubts on a possible detrimental role of this conductive polymer. Here, we propose the use of [2-(9H-carbazol-9-yl)ethyl]phosphonic acid (2PACz) and [2-(3, 6-dibromo-9H-carbazol-9-yl) ethyl] phosphonic acid (Br-2PACz) as substitutes for PEDOT:PSS. By using Cs0.25FA0.75Sn0.5Pb0.5I3 as the active layer, we obtained record efficiencies as high as 19.51% on Br-2PACz, while 18.44% and 16.33% efficiencies were obtained using 2PACz and PEDOT:PSS, respectively. In addition, the implemented monolayers enhance both the shelf lifetime of the device as well as the operational stability. Finally, the Br-2PACz-based devices maintained 80% of their initial efficiency under continuous illumination for 230 h, and after being stored in a N2 atmosphere for 4224 h (176 days).\nThe dataset contains raw and processed data used in the manuscript. You can find all the data in different folders named \"Figure 1\", \"Figure 2\"..."},"dsDescriptionDate":{"typeName":"dsDescriptionDate","multiple":false,"typeClass":"primitive","value":"2023-11-16"}}]},{"typeName":"subject","multiple":true,"typeClass":"controlledVocabulary","value":["Physics"]},{"typeName":"keyword","multiple":true,"typeClass":"compound","value":[{"keywordValue":{"typeName":"keywordValue","multiple":false,"typeClass":"primitive","value":"carbazole-based Self-assembled monolayer"}},{"keywordValue":{"typeName":"keywordValue","multiple":false,"typeClass":"primitive","value":"halogen functionalization"}},{"keywordValue":{"typeName":"keywordValue","multiple":false,"typeClass":"primitive","value":"mixed tin/lead perovskite"}},{"keywordValue":{"typeName":"keywordValue","multiple":false,"typeClass":"primitive","value":"stability"}},{"keywordValue":{"typeName":"keywordValue","multiple":false,"typeClass":"primitive","value":"perovskite solar cell"}},{"keywordValue":{"typeName":"keywordValue","multiple":false,"typeClass":"primitive","value":"liquid-phase deposition"}}]},{"typeName":"topicClassification","multiple":true,"typeClass":"compound","value":[{"topicClassValue":{"typeName":"topicClassValue","multiple":false,"typeClass":"primitive","value":"Material Science"}},{"topicClassValue":{"typeName":"topicClassValue","multiple":false,"typeClass":"primitive","value":"Optoelectronic"}}]},{"typeName":"publication","multiple":true,"typeClass":"compound","value":[{"publicationCitation":{"typeName":"publicationCitation","multiple":false,"typeClass":"primitive","value":"Pitaro, M., Alonso, J. S., Di Mario, L., Garcia Romero, D., Tran, K., Zaharia, T., Johansson, M. B., Johansson, E. M. J., & Loi, M. A. (2023). A carbazole-based self-assembled monolayer as the hole transport layer for efficient and stable Cs0.25FA0.75Sn0.5Pb0.5I3 solar cells. Journal of Materials Chemistry A, 11(22), 11755-11766."},"publicationIDType":{"typeName":"publicationIDType","multiple":false,"typeClass":"controlledVocabulary","value":"doi"},"publicationURL":{"typeName":"publicationURL","multiple":false,"typeClass":"primitive","value":"https://doi.org/10.1039/D3TA01276J"}}]},{"typeName":"language","multiple":true,"typeClass":"controlledVocabulary","value":["English"]},{"typeName":"depositor","multiple":false,"typeClass":"primitive","value":"Silva Correia Alves, Ana"},{"typeName":"dateOfDeposit","multiple":false,"typeClass":"primitive","value":"2023-11-08"}]},"dansDataVaultMetadata":{"displayName":"Data Vault Metadata","name":"dansDataVaultMetadata","fields":[{"typeName":"dansDataversePid","multiple":false,"typeClass":"primitive","value":"doi:10.34894/SAXZOK"},{"typeName":"dansDataversePidVersion","multiple":false,"typeClass":"primitive","value":"1.0"},{"typeName":"dansBagId","multiple":false,"typeClass":"primitive","value":"urn:uuid:847c9a59-fbc6-4f0c-83bd-675155c1253a"},{"typeName":"dansNbn","multiple":false,"typeClass":"primitive","value":"urn:nbn:nl:ui:13-e7a81287-6569-4e34-acde-1c3b997ca92c"}]}},"files":[{"label":"Data for all the figures present on the papers","restricted":false,"version":1,"datasetVersionId":25513,"dataFile":{"id":384681,"persistentId":"","filename":"Data for all the figures present on the papers","contentType":"application/x-rar-compressed","friendlyType":"RAR Archive","filesize":32453315,"storageIdentifier":"surf://store:18bc993053b-145551049892","rootDataFileId":-1,"checksum":{"type":"SHA-1","value":"32d738f7cf8b50fba769298de892aa2047beebeb"},"tabularData":false,"creationDate":"2023-11-13","publicationDate":"2023-11-16","lastUpdateTime":"2023-11-16T15:37:31Z","fileAccessRequest":false}}]}}}