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It contains a positive and negative polarity ToF-SIMS image of Sample 1, a positive polarity MS/MS image of Sample 2, and a positive polarity MS/MS image of Sample 3. TOF-SIMS analyses were performed on a PHI nanoTOF II instrument (Physical Electronics, Chanhassen, MN, USA) equipped with a 30keV Bi<sub>n</sub><sup>q+</sup> liquid metal ion gun (LMIG) used as an analysis beam, and an Ar gas cluster ion beam (GCIB; 10keV) for nondestructive sputter cleaning."}}]},{"typeName":"subject","multiple":true,"typeClass":"controlledVocabulary","value":["Chemistry"]},{"typeName":"keyword","multiple":true,"typeClass":"compound","value":[{"keywordValue":{"typeName":"keywordValue","multiple":false,"typeClass":"primitive","value":"imaging mass spectrometry"}},{"keywordValue":{"typeName":"keywordValue","multiple":false,"typeClass":"primitive","value":"ToF-SIMS"}}]},{"typeName":"publication","multiple":true,"typeClass":"compound","value":[{"publicationCitation":{"typeName":"publicationCitation","multiple":false,"typeClass":"primitive","value":"Anal. Chem. 2025, 97, 2, 1054–1058"},"publicationIDType":{"typeName":"publicationIDType","multiple":false,"typeClass":"controlledVocabulary","value":"doi"},"publicationIDNumber":{"typeName":"publicationIDNumber","multiple":false,"typeClass":"primitive","value":"10.1021/acs.analchem.4c05523"},"publicationURL":{"typeName":"publicationURL","multiple":false,"typeClass":"primitive","value":"https://doi.org/10.1021/acs.analchem.4c05523"}}]},{"typeName":"notesText","multiple":false,"typeClass":"primitive","value":"The RAW files can be accessed using the commercial PHI software (TOF-DR 3.3.0.19)."},{"typeName":"productionPlace","multiple":true,"typeClass":"primitive","value":["Maastricht University, Maastricht, The Netherlands"]},{"typeName":"depositor","multiple":false,"typeClass":"primitive","value":"Van Nuffel, Sebastiaan"},{"typeName":"dateOfDeposit","multiple":false,"typeClass":"primitive","value":"2024-10-09"},{"typeName":"dateOfCollection","multiple":true,"typeClass":"compound","value":[{"dateOfCollectionStart":{"typeName":"dateOfCollectionStart","multiple":false,"typeClass":"primitive","value":"2024-03-15"},"dateOfCollectionEnd":{"typeName":"dateOfCollectionEnd","multiple":false,"typeClass":"primitive","value":"2024-06-17"}}]},{"typeName":"software","multiple":true,"typeClass":"compound","value":[{"softwareName":{"typeName":"softwareName","multiple":false,"typeClass":"primitive","value":"SmartSoft"}}]}]},"dansDataVaultMetadata":{"displayName":"Data Vault Metadata","name":"dansDataVaultMetadata","fields":[{"typeName":"dansDataversePid","multiple":false,"typeClass":"primitive","value":"doi:10.34894/LRIH3A"},{"typeName":"dansDataversePidVersion","multiple":false,"typeClass":"primitive","value":"1.1"},{"typeName":"dansBagId","multiple":false,"typeClass":"primitive","value":"urn:uuid:95ee4e19-e9a3-4e7d-9522-76d8e413f51a"},{"typeName":"dansNbn","multiple":false,"typeClass":"primitive","value":"urn:nbn:nl:ui:13-8a6d7159-d447-410f-94b7-7cc74e10e1fe"}]}},"files":[{"description":"Main Figure 2.","label":"016_Pos_VG_B_20240617.raw","restricted":false,"version":1,"datasetVersionId":30139,"dataFile":{"id":453366,"persistentId":"","filename":"016_Pos_VG_B_20240617.raw","contentType":"image/RAW","friendlyType":"Bitmap Image","filesize":654947250,"description":"Main Figure 2.","embargo":{"dateAvailable":"2024-12-31"},"storageIdentifier":"surf://store:19271bd7462-235fcccd065b","rootDataFileId":-1,"checksum":{"type":"SHA-1","value":"16079d8cf4d7dbd653c3b8412777208a88d1b345"},"tabularData":false,"creationDate":"2024-10-09","publicationDate":"2024-10-11","lastUpdateTime":"2025-01-28T10:54:51Z","fileAccessRequest":true}},{"description":"Supplementary Figure 5.","label":"018_Pos_VG_20240315.raw","restricted":false,"version":1,"datasetVersionId":30139,"dataFile":{"id":453365,"persistentId":"","filename":"018_Pos_VG_20240315.raw","contentType":"image/RAW","friendlyType":"Bitmap Image","filesize":390539789,"description":"Supplementary Figure 5.","embargo":{"dateAvailable":"2024-12-31"},"storageIdentifier":"surf://store:19271bf1305-36835d890332","rootDataFileId":-1,"checksum":{"type":"SHA-1","value":"0f6d020c7f8b2a42e7f89697f5f0bed70c13ad5b"},"tabularData":false,"creationDate":"2024-10-09","publicationDate":"2024-10-11","lastUpdateTime":"2025-01-28T10:54:51Z","fileAccessRequest":true}},{"description":"Main Figure 1.","label":"054_Neg_VG_A_20240531.raw","restricted":false,"version":1,"datasetVersionId":30139,"dataFile":{"id":453364,"persistentId":"","filename":"054_Neg_VG_A_20240531.raw","contentType":"image/RAW","friendlyType":"Bitmap Image","filesize":55792016,"description":"Main Figure 1.","embargo":{"dateAvailable":"2024-12-31"},"storageIdentifier":"surf://store:19271bf54cb-180a64d6cba7","rootDataFileId":-1,"checksum":{"type":"SHA-1","value":"2e61b0f990cff350e5708a2918753cd1577b3347"},"tabularData":false,"creationDate":"2024-10-09","publicationDate":"2024-10-11","lastUpdateTime":"2025-01-28T10:54:51Z","fileAccessRequest":true}},{"description":"Main Figure 1.","label":"060_Pos_VG_A_20240531.raw","restricted":false,"version":1,"datasetVersionId":30139,"dataFile":{"id":453363,"persistentId":"","filename":"060_Pos_VG_A_20240531.raw","contentType":"image/RAW","friendlyType":"Bitmap Image","filesize":88688649,"description":"Main Figure 1.","embargo":{"dateAvailable":"2024-12-31"},"storageIdentifier":"surf://store:19271bfad01-696f400fe33d","rootDataFileId":-1,"checksum":{"type":"SHA-1","value":"4d2853b43e87a4baeaae9b8795c1d02296f54905"},"tabularData":false,"creationDate":"2024-10-09","publicationDate":"2024-10-11","lastUpdateTime":"2025-01-28T10:54:51Z","fileAccessRequest":true}}]}}}