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While the relationship between rate and equilibrium constants (REC’s) and bulk mechanical properties is increasingly explored, less known is the effect of network topology or cross-linker length on both REC’s and mechanical properties in dynamically cross-linked hydrogels. Here, we chose hydrazone formation as a model system for dynamic covalent network formation. Using mono- and bi-valent hydrazides with molecular weights of 0.1–20 kg·mol-1, we show that their chemical reactivity with a small molecule aldehyde is largely unaffected by their length. However, the apparent reactivity between two polymeric macromers revealed a decade reduction in k1 and Keq compared to the model system. We then studied the impact of different cross-linkers on hydrogel mechanics, revealing a reduction in G′ of 1.3–2.5-fold (cross-linker length) vs 18–28-fold (cross-linker valency), along with emergent strain-stiffening behavior. Finally, we offer potential mechanisms for these observations. 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